Classifications

Pictogram Usage
GHS-pictogram-explos.svg 
  • Unstable explosives
  • Explosives, divisions 1.1, 1.2, 1.3, 1.4, 1.5, 1.6
  • Self-reactive substances and mixtures, types A, B
  • Organic peroxides, types A, B
GHS01: Explosive
GHS-pictogram-flamme.svg 
  • Flammable gases, category 1
  • Flammable aerosols, categories 1, 2
  • Flammable liquids, categories 1, 2, 3, 4
  • Flammable solids, categories 1, 2
  • Self-reactive substances and mixtures, types B, C, D, E, F
  • Pyrophoric liquids, category 1
  • Pyrophoric solids, category 1
  • Combustible solids, category 3
  • Combustible liquids, category 3
  • Self-heating substances and mixtures, categories 1, 2
  • Substances and mixtures, which in contact with water, emit flammable gases, categories 1, 2, 3
  • Organic peroxides, types B, C, D, E, F

 

GHS02: Flammable
GHS-pictogram-rondflam.svg 
  • Oxidizing gases, category 1
  • Oxidizing liquids, categories 1, 2, 3
  • Oxidizing solids, categories 1, 2, 3
GHS03: Oxidizing
GHS-pictogram-bottle.svg 
GHS04: Compressed Gas
GHS-pictogram-acid.svg 
  • Corrosive to metals, category 1
GHS05: Corrosive
  
  • Explosives, divisions 1.5, 1.6
  • Flammable gases, category 2
  • Self-reactive substances and mixtures, type G
  • Organic peroxides, type G
no pictogram required
   
GHS-pictogram-skull.svg 
  • Acute toxicity (oral, dermal, inhalation), categories 1, 2, 3
  • e.g. Manganese Heptoxide (fire diamond rating at health hazard is 4)
GHS06: Toxic
GHS-pictogram-exclam.svg 
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    • Respiratory tract irritation
    • Narcotic effects
  • with the “skull and crossbones” pictogram
  • for skin or eye irritation if:
    • the “corrosion” pictogram also appears
    • the “health hazard” pictogram is used to indicate respiratory sensitization

 

GHS07: Harmful
GHS-pictogram-silhouette.svg 
  • Respiratory sensitization, category 1
  • Germ cell mutagenicity, categories 1A, 1B, 2
  • Carcinogenicity, categories 1A, 1B, 2
  • Reproductive toxicity, categories 1A, 1B, 2
  • Specific target organ toxicity following single exposure, categories 1, 2
  • Specific target organ toxicity following repeated exposure, categories 1, 2
  • Aspiration hazard, categories 1, 2
  • e.g. Chromium

 

GHS08: Health hazard
  
  • Acute toxicity (oral, dermal, inhalation), category 5
  • Eye irritation, category 2B
  • Reproductive toxicity – effects on or via lactation
no pictogram required
   
GHS-pictogram-pollu.svg 
  • Acute hazards to the aquatic environment, category 1
  • Chronic hazards to the aquatic environment, categories 1, 2
  • Environmental toxicity, categories 1, 2
GHS09: Environmental hazard
  
  • Acute hazards to the aquatic environment, categories 2, 3
  • Chronic hazards to the aquatic environment, categories 3, 4
no pictogram required

 

General Precautionary Statements

P101If medical advice is needed, have product container or label at hand.
P102Keep out of reach of children.
P103Read label before use

Prevention Precautionary Statements

P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P210Keep away from heat, hot surface, sparks, open flames and other ignition sources. – No smoking.
P211Do not spray on an open flame or other ignition source.
P212Avoid heating under confinement or reduction of the desensitized agent.
P220Keep away from clothing and other combustible materials.
P221Take any precaution to avoid mixing with combustibles/…
P222Do not allow contact with air.
P223Do not allow contact with water.
P230Keep wetted with …
P231Handle under inert gas.
P232Protect from moisture.
P233Keep container tightly closed.
P234Keep only in original container.
P235Keep cool.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof [electrical/ventilating/lighting/…/] equipment.
P242Use only non-sparking tools.
P243Take precautionary measures against static discharge.
P244Keep valves and fittings free from oil and grease.
P250Do not subject to grinding/shock/friction/…
P251Do not pierce or burn, even after use.
P260Do not breathe dust/fume/gas/mist/vapors/spray.
P261Avoid breathing dust/fume/gas/mist/vapors/spray.
P262Do not get in eyes, on skin, or on clothing.
P263Avoid contact during pregnancy/while nursing.
P264Wash … thoroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P272Contaminated work clothing should not be allowed out of the workplace.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P281Use personal protective equipment as required.
P282Wear cold insulating gloves/face shield/eye protection.
P283Wear fire resistant or flame retardant clothing.
P284[In case of inadequate ventilation] Wear respiratory protection.
P285In case of inadequate ventilation wear respiratory protection.
P231+P232Handle under inert gas/… Protect from moisture.
P235+P410Keep cool. Protect from sunlight.

Response Precautionary Statements

P301IF SWALLOWED:
P302IF ON SKIN:
P303IF ON SKIN (or hair):
P304IF INHALED:
P305IF IN EYES:
P306IF ON CLOTHING:
P307IF exposed:
P308IF exposed or concerned:
P309IF exposed or if you feel unwell
P310Immediately call a POISON CENTER or doctor/physician.
P311Call a POISON CENTER or doctor/…
P312Call a POISON CENTER or doctor/… if you feel unwell.
P313Get medical advice/attention.
P314Get medical advice/attention if you feel unwell.
P315Get immediate medical advice/attention.
P320Specific treatment is urgent (see … on this label).
P321Specific treatment (see … on this label).
P322Specific measures (see …on this label).
P330Rinse mouth.
P331Do NOT induce vomiting.
P332IF SKIN irritation occurs:
P333If skin irritation or rash occurs:
P334Immerse in cool water [or wrap in wet bandages].
P335Brush off loose particles from skin.
P336Thaw frosted parts with lukewarm water. Do not rub affected area.
P337If eye irritation persists:
P338Remove contact lenses, if present and easy to do. Continue rinsing.
P340Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342If experiencing respiratory symptoms:
P350Gently wash with plenty of soap and water.
P351Rinse cautiously with water for several minutes.
P352Wash with plenty of water/…
P353Rinse skin with water [or shower].
P360Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361Take off immediately all contaminated clothing.
P362Take off contaminated clothing.
P363Wash contaminated clothing before reuse.
P364And wash it before reuse.[Added in 2015 version]
P370In case of fire:
P371In case of major fire and large quantities:
P372Explosion risk.
P373DO NOT fight fire when fire reaches explosives.
P374Fight fire with normal precautions from a reasonable distance.
P376Stop leak if safe to do so.
P377Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378Use … to extinguish.
P380Evacuate area.
P381In case of leakage, eliminate all ignition sources.
P390Absorb spillage to prevent material damage.
P391Collect spillage.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER/doctor/…
P301+P312IF SWALLOWED: call a POISON CENTER/doctor/… IF you feel unwell.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P334IF ON SKIN: Immerse in cool water [or wrap in wet bandages].
P302+P335+P334Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].
P302+P350IF ON SKIN: Gently wash with plenty of soap and water.
P302+P352IF ON SKIN: wash with plenty of water.
P303+P361+P353IF ON SKIN (or hair): Take off Immediately all contaminated clothing. Rinse SKIN with water [or shower].
P304+P312IF INHALED: Call a POISON CENTER/doctor/… if you feel unwell.
P304+P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P304+P341IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P306+P360IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307+P311IF exposed: call a POISON CENTER or doctor/physician.
P308+P311IF exposed or concerned: Call a POISON CENTER/doctor/…
P308+P313IF exposed or concerned: Get medical advice/attention.
P309+P311IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.
P335+P334Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337+P313IF eye irritation persists: Get medical advice/attention.
P342+P311IF experiencing respiratory symptoms: Call a POISON CENTER/doctor/…
P361+P364Take off immediately all contaminated clothing and wash it before reuse.
P362+P364Take off contaminated clothing and wash it before reuse.
P370+P376in case of fire: Stop leak if safe to do so.
P370+P378In case of fire: Use … to extinguish.
P370+P380In case of fire: Evacuate area.
P370+P380+P375In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371+P380+P375In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.

Storage Precautionary Statements

P401Store in accordance with …
P402Store in a dry place.
P403Store in a well-ventilated place.
P404Store in a closed container.
P405Store locked up.
P406Store in corrosive resistant/… container with a resistant inner liner.
P407Maintain air gap between stacks or pallets.
P410Protect from sunlight.
P411Store at temperatures not exceeding … °C/…°F.
P412Do not expose to temperatures exceeding 50 °C/ 122 °F.
P413Store bulk masses greater than … kg/…lbs at temperatures not exceeding … °C/…°F.
P420Store separately.
P422Store contents under …
P402+P404Store in a dry place. Store in a closed container.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P403+P235Store in a well-ventilated place. Keep cool.
P410+P403Protect from sunlight. Store in a well-ventilated place.
P410+P412Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122°F.
P411+P235Store at temperatures not exceeding … °C/…°F. Keep cool.

Disposal Precautionary Statements

P501Dispose of contents/container to …
P502Refer to manufacturer or supplier for information on recovery or recycling
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